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Google Scholar profile: K. Travis Holman
ORCID: http://orcid.org/0000-0003-1800-300X

Publications in press/print.

H(Hirsch)-index (Google Scholar) of K. Travis Holman (April-22): 31
(*) denotes GU undergraduate student co-author; denotes Corresponding Author


Georgetown University…
Submitted:
  • 78. Ramirez, Joseph R. and Holman, K. Travis “A High Porosity, Gmelinite Form of Zinc Imidazolate (GME-ZnIm2), by the Hectogram," submitted.
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Published and In Press:
  • 77. Kelly, Andrew W. and Holman, K. Travis “Click”-Like η6-Metalation/Demetalation of Aryl Iodides as a Means of Turning “ON/OFF” Halogen Bond Donor Functionality), Angew. Chem.Int. Ed. 2022, 61, e20211555. (article) https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202115556
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  • 76. Brekalo, Ivana; Deliz (*), David; Kane, Christopher M.; Friščić, Tomislav; Holman, K. Travis “Exploring the scope of macrocyclic “shoe-last” templates in the mechanochemical synthesis of RHO topology Zeolitic Imidazolate Frameworks (ZIFs),” Molecules 2020, 25(3), 633. (article) https://doi.org/10.3390/molecules25030633 (invited contribution as part of the special issue on Recent Development of Mechanochemical Synthesis)
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  • 75. Hammud, Hassan H.; Holman, K. Travis; Al-Noaimi, Mousa; Sadiq Sheik, Nadeem; Ghannoum, Amer M.; Bouhadir, Kamal H.; Masoud, Mamdouh S.; Kumar Karnati, Ranjith “Structures of selected transition metal complexes with 9-(2-hydroxyethyl)adenine: Potentiometric complexation and DFT studies,” J. Mol. Struct. 2020, DOI:10.1016/j.molstruc.2019.127548. (article) https://doi.org/10.1016/j.molstruc.2019.127548
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  • 74. Brekalo, Ivana; Yuan, Wenbing; Mottillo, Cristina; Lu, Yuneng ; Zhang, Yuancheng; Casaban, Jose; Holman, K. Travis; James, Stuart L.; Duarte, Frédéric; Williams, P. Andrew; Harris, Kenneth D. M.; Friščić, Tomislav “Manometric real-time studies of the mechanochemical synthesis of zeolitic imidazolate frameworks,” Chem. Sci. 2020, DOI: 10.1039/C9SC05514B. (article) https://pubs.rsc.org/en/content/articlelanding/2020/SC/C9SC05514B
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  • 73. Brekalo, I.; Deliz, D. E.(*); Barbour, L. J.; Ward, M. D.; Friščić, T.; Holman, K. T. "Microporosity of a Guanidinium Organodisulfonate Hydrogen‐Bonded Framework" Angew. Chem. Int. Ed. 2020, 59, 1997–2002.  DOI: 10.1002/anie.20191186. (communication) https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201911861
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  • 72. Brekalo, I.; Kane, C. M.; Ley, A. N.; Ramirez, J. R.; Friščić, T.; Holman, K. T. "Use of a 'Shoe-Last' Solid-State Template in the Mechanochemical Synthesis of High-Porosity RHO-Zinc Imidazolate" J. Am. Chem. Soc. 2018, 140(32), pp 10104–10108. (communication). DOI: 10.1021/jacs.8b0547; https://pubs.acs.org/doi/10.1021/jacs.8b05471
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  • 71. El-Ayle, G.; Holman, K. T. "Cryptophanes," In Comprehensive Supramolecular Chemistry II; Atwood, J.L., Gokel, G. W., Barbour, L. J., Eds.; Elsevier: New York, 2017; Vol. 6, 199-249. (review).  http://dx.doi.org/10.1016/B978-0-12-409547-2.13925-3
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Cryptophanes_CSC-II.pdf
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  • 70. Ramirez, Joseph R.; Yang, Haiyang(*); Kane, Christopher M.; Ley, Amanda N.; Holman, K. Travis “Reproducible Synthesis and High Porosity of mer-Zn(Im)2 (ZIF-10): Exploitation of an Apparent Double-Eight Ring Template,” J. Am. Chem. Soc. 2016, 138, 12017−12020.  (communication) DOI: 10.1021/jacs.6b06375;  http://pubs.acs.org/doi/abs/10.1021/jacs.6b06375​
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  • 69.   Kane, Christopher M.; Banisafar, Arash(*); Dougherty, Timothy P.(*); Barbour, Leonard J.; Holman, K. Travis “Enclathration and Confinement of Small Gases by the Intrinsically 0D Porous Molecular Solid, Me,H,SiMe2,” J. Am. Chem. Soc. 2016, 138, 4377–4392.  (full paper)  DOI: 10.1021/jacs.5b11395;​http://pubs.acs.org/doi/abs/10.1021/jacs.5b11395
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  • 68.   Kane, C. M.; Ugono, O.; Barbour, L. J.; Holman, K. T. “Many Simple Molecular Cavitands are Intrinsically Porous (Zero-dimensional Pore) Materials,” Chem. Mater. 2015, 27, 7337–7354. (full paper)  DOI: 10.1021/acs.chemmater.5b02972; http://pubs.acs.org/doi/10.1021/acs.chemmater.5b02972
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  • 67.   Abourahma, H.; Shah, D. D.; Melendez, J. D.; Johnson, E. J.; Holman, K. T. “A Tale of Two Stoichiometrically Diverse Cocrystals,” Cryst. Growth Des., 2015, 15(7), 3101–3104. (communication) DOI: 10.1021/acs.cgd.5b00357; http://pubs.acs.org/doi/abs/10.1021/acs.cgd.5b00357
  • 66.   Joseph, A. I.; Lapidus, S. H.; Kane, C. M.; Holman, K. T. “Extreme confinement of xenon by cryptophane-111 in the solid state,” Angew. Chem. Int. Ed. 2015, 54, 1471–1475. (communication) DOI: 10.1002/anie.201409415; http://onlinelibrary.wiley.com/doi/10.1002/anie.201409415/abstract
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  • 65.   Tosso, P. N.; Kong, Y. L.; Scher, L.; Cummins, R.; Schneider, J.; Rahim, S.; Holman, K. T.; Toretsky, J.; Wang, K.; Uren, A.; Brown, M. L. “Synthesis and Structure Activity Relationship Studies of Small Molecule Disruptors of EWS-FLI1 Interactions in Ewing's Sarcoma,” J. Med. Chem. 2014, 57, 10290-10303.  (full paper) DOI: 10.1021/jm501372p http://pubs.acs.org/doi/abs/10.1021/jm501372p
  • 64.   Joseph, A. I.; El-Ayle, G.; Boutin, C.; Léonce, E.; Berthault, P.; Holman, K. T. “Rim-functionalized cryptophane-111 derivatives via heterocapping, and their xenon complexes,” Chem. Commun. 2014, 50, 15905-15908.  (communication) DOI: 10.1039/C4CC08001G; http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/C4CC08001G
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  • 63.   Kerr, A. T.; Kumalah, S. A.; Holman, K. T.; Butcher, R. T.; Cahill, C. L. “Uranyl Coordination Polymers Incorporating h5-Cyclopentadienyliron-Functionalized h6-Phthalate Metalloligands: Syntheses, Structures and Photophysical Properties” J. Inorg. Organomet. Polym. 2014, 24, 128-136.  (full paper; invited contribution to special issue in memory of Prof. Dwight A. Sweigart)  http://link.springer.com/article/10.1007/s10904-013-9980-0/fulltext.html
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  • 62.   Arshad, M. N.; I. U.; Zia-ur-Rehman; Khan, I. U.; Mustafa, G.; Shafiq, M.; Rafique, H. M.; Holman, K. T. “Structural studies of  2-pentyl/pentenyl-substituted methyl 4-hydroxy-2H-1, 2-benzothiazine-3-carboxylate-1,1-dioxide” Walailak Journal of Science and Technology 2012, 9, 375-380. http://wjst.wu.ac.th/index.php/wjst/article/download/246/244
  • 61.   Arshad, M. N.; Khan, I. U.; Zia-ur-Rehman, M.; Danish, M.; Holman, K. T. “Methyl 2-(but-3-enyl)-4-hydroxy-1,1-dioxo-2H-1l6, 2-benzothiazine-3-carboxylate” Acta Cryst. 2012, E68, o1926. (note) DOI:10.1107/S1600536812022908. http://journals.iucr.org/e/issues/2012/06/00/bt5926/bt5926.pdf
  • 60.   Arshad, M. N.; Khan, I. U.; Zia-ur-Rehman, M.; Danish, M.; Holman, K. T. “Methyl 4-hydroxy-1,1-dioxo-2-(2-phenylethyl)-2H-1l6, 2-benzothiazine-3-carboxylate” Acta Cryst. 2011, E67, o3445-u340. (note) DOI: 10.1107/S160053681104966X. http://journals.iucr.org/e/issues/2011/12/00/hb6520/hb6520.pdf
  • 59.   Pablico, M. H.; Mertzman, J. E.; Japp, E. A.; Boncher, W. L.; Nishida, M.; Keuren, E. V.; Lofland, S.; Dollahon, N.; Rubinson, J. F.; Holman, K. T.; Stoll, S. L. “Miniemulsion synthesis of metal-oxo cluster containing copolymer nanobeads,” Langmuir, 2011, 27, 12575-12584. (full paper)http://pubs.acs.org/doi/abs/10.1021/la2029774
  • 58.   Arshad, M. N.; Khan, I. U.; Holman, K. T.; Asiri, A. M.; Rafique, H. M. “N-(2-Bromophenyl)-4-methyl-N-(4-methylphenylsulfonyl)benzenesulfonamide” Acta Cryst. 2011, E67, o2356-o2357. (note)  DOI: 10.1107/S1600536811032533. http://journals.iucr.org/e/issues/2011/09/00/pv2443/index.html
  • 57.   Mallia, V. A.; Butler, P.D.; Sarkar, B.; Holman, K. T.; Weiss, R. G. “Reversible phase transitions within self-assembled fibrillar networks of (R)-18-(n-alkylamino)octadecan-7-ols in their carbon tetrachloride gels,” J. Am. Chem. Soc. 2011, 133, 15045-15054. (full paper) http://pubs.acs.org/doi/abs/10.1021/ja204371b
  • 56.   Arshad, M. N.; Khan, I. U.; Zia-ur-Rehman, M.; Rafique, H. M.; Holman. K. T. “Methyl 4-hydroxy-2-isopropyl-1,1-dioxo-2H-1,2-benzothiazine-3-carboxylate” Acta Cryst. 2011, E67, o1823-o1824. (note)  DOI: 10.1107/S1600536811024573.  http://journals.iucr.org/e/issues/2011/07/00/im2299/index.html
  • 55.   Holman, K. T. “Molecule-constructed Microporous Materials: long under our noses, increasingly on our tongues, and now in our bellies,” Angew. Chem Int. Ed. 2011, 50, 1228-1230. (highlight, invited)  http://onlinelibrary.wiley.com/doi/10.1002/anie.201006783/abstract
  • 54.   Kumalah Robinson, S. A.; Mempin, M.-V. L.(*); Cairns, A. J.; Holman, K. T. “A cubic, 12-connected, microporous metal-organometallic phosphate framework sustained by truncated tetrahedral nodes,” J. Am. Chem. Soc. 2011, 133, 1634-1637. (communication) http://pubs.acs.org/doi/abs/10.1021/ja108894a
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  • 53.   Mubashar-ur-Rehman, H.; Khan, I. U.; Arshad, M. N.; Holman, K. T. “(2S)-3-Carbamoyl-2-(4-methoxybenzenesulfonamido) propanoic acid” Acta Cryst. 2010, E66, o2596. (note) http://journals.iucr.org/e/issues/2010/10/00/hb5624/index.html
  • 52.   Fairchild, R. M.; Joseph, A. I.; Holman, K. T.; Fogarty, H. A.; Brotin, T.; Dutasta, J.-P.; Boutin, C.; Huber, G.; Berthault, P. “A water soluble Xe@cryptophane-111 complex exhibits very high thermodynamic stability and a peculiar 129Xe NMR chemical shift” J. Am. Chem. Soc. 2010, 132, 15505-15507. (communication) http://pubs.acs.org/doi/abs/10.1021/ja1071515
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  • 51.   Holman, K. T., Drake, S. D.; Orr, G. W.; Steed, J. W.; Atwood, J. L. “Anion binding, aryl-extended cyclotriguaiacylenes and an aryl bridged cryptophane that provides snapshots of a molecular gating mechanism” Supramol. Chem. 2010, 22, 870-890. (full paper; invited contribution to special issue in memory of Prof. Dmitry M. Rudkevich) http://www.tandfonline.com/doi/abs/10.1080/10610278.2010.514615  [pdf]
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SupramolChem_2010_870-890.pdf
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  • 50.   Kane, C. M.; Drake, S. D.; Holman, K. T. “ 2-[4-(2,6-dimethoxyphenyl)butyl]-1,3-dimethoxybenzene” Acta Cryst. 2010, E66, o1921. (note)          http://journals.iucr.org/e/issues/2010/08/00/ng2784/index.html
  • 49.   Arshad, M. N.; Zumberge, K.(*); Mough, S. T.; Holman, K. T. “1,3-Bis(bromomethyl)-2-nitrobenzene” Acta Cryst. 2010, E66, o834. (note) http://journals.iucr.org/e/issues/2010/04/00/ng2729/index.html
  • 48.   Arshad, M. N.; Mough, S. T.; Goeltz, J. C.(*); Holman, K. T. “3,5-Bis-(4-hydroxymethyl-2-methoxy-phenoxymethyl)-benzoic acid methyl ester” Acta Cryst. 2010, E66, o703. (note) http://journals.iucr.org/e/issues/2010/03/00/ng2730/index.html
  • 47.   Arshad, M. N.; Bader, M. M.; Pham, P.-T. T.; Holman, K. T.  “(1E,3E,5E,7E )-4,4’-(Octa-1,3,5,7-tetraene-1,8-diyl)dipyridine” Acta Cryst. 2010, E66, o508. (note) http://journals.iucr.org/e/issues/2010/03/00/ng2706/index.html
  • 46.   Mathrubootham, V.; Addison, A. W.; Holman, K. T.; Sinn, E.; Thompson, L. K. “A novel copper(II) complex of a tripodal ligand with phenolate-phenol interligand, intramolecular hydrogen bonding” Dalton Trans. 2009, 8111-8116. (full paper) http://pubs.rsc.org/en/Content/ArticleLanding/2009/DT/B910188H
  • 45.  Kumalah, S. A.; Holman, K. T. “Polymorphism and Inclusion Properties of 3D Metal-Organometallic Frameworks of an h6-Metalated Terephthalate Ligand”, Inorg. Chem. 2009, 48, 6860-6872. (full paper) http://pubs.acs.org/doi/abs/10.1021/ic900816h
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  • 44.  Hammud, H. H.; Holman, K. T.; Masoud, M.S.; El-Faham, A.; Beidas H. "1-Hydroxybenzotriazole (HOBt) acidity, formation constant with different metals and thermodynamic parameters. Synthesis and characterization of some HOBt metal complexes.  Crystal structures of two polymers: [Cu2(H2O)5(OBt)2(m-OBt2)]·2H2O·EtOH (1A) and [Cu(m-OBt)(HOBt)(OBt)(EtOH)] (1B)" Inorg. Chim. Acta. 2009, 262, 3526-3540.  (full paper)
  • 43.  Deifel, N. P.; Holman, K. T.; Cahill, C. L. “PF6- Hydrolysis as a Route to Unique Uranium Phosphate Materials,” Chem. Commun. 2008, 6037-6038.  (communication) http://pubs.rsc.org/en/Content/ArticleLanding/2008/CC/B813819B
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  • 42. Fairchild, R. M.; Holman, K. T. “[(h5-C5Me4CH2R)Ru(h6-arene)]+ and [(h5-C5Me4CH2R)Ru(CH3CN)3]+ Compounds Possessing Pendant Arms,” Organometallics 2008, 27, 1823-1833. (full paper) http://pubs.acs.org/doi/abs/10.1021/om701084m
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  • 41.  Mough, S. T.; Holman, K. T. “A soft coordination polymer derived from container molecule ligands,” Chem. Commun. 2008, 1407-1409.  (communication) http://pubs.rsc.org/en/Content/ArticleLanding/2008/CC/B715339B
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  • 40.  Ugono, O.; Moran, J. P.(*); Holman, K. T. “Chiral, closed-surface, metal-organic nanocapsules derived from cavitand ligands,” Chem. Commun., 2008, 1404-1406.  (communication) http://pubs.rsc.org/en/Content/ArticleLanding/2008/CC/B715273F
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  • 39.  Horner, M. J.; Holman, K. T.; Ward, M. D. “Architectural Diversity and Elastic Networks in Hydrogen-Bonded Host Frameworks:  From Molecular Jaws to Cylinders” J. Am. Chem. Soc. 2007,129, 14640-14660.  (full paper) http://pubs.acs.org/doi/abs/10.1021/ja0741574
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  • 38.  Fairchild, R. M.; Holman, K. T. “Facile, Near-Quantitative, Aqueous Routes to Nearly any [Cp*Ru(arene)]Cl Compound” Organometallics 2007, 26, 3049-3053.  Addition/correction: - - -, ibid., 4086.  (note) http://pubs.acs.org/doi/abs/10.1021/om0701773
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  • 37.  Ugono, O.; Holman, K. T. “An achiral form of the hexameric resorcin[4]arene capsule sustained by hydrogen bonding with alcohols” Chem. Commun. 2006, 2144-2146.  (communication, selected as “Hot Paper”) http://pubs.rsc.org/en/Content/ArticleLanding/2006/CC/B604148E
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  • 36. Alizadeh, M.; Holman, K. T.; Mirzaeia, M.; Razavi, H. “Triprolinium 12-phosphomolybdate: Synthesis, Crystal Structure and Properties of [C5H10NO2]3[PMo12O40]∙4.5H2O” Polyhedron 2006, 25, 1567-1570.  (full paper)
  • 35.  Fairchild, R. M.; Holman, K. T. “Selective anion encapsulation by a metalated cryptophane with a p-acidic interior,” J. Am. Chem. Soc. 2005, 127, 16364-16365.  (communication) http://pubs.acs.org/doi/abs/10.1021/ja055560i
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  • 34. Holman, K. T.; Hammud, H. H.; Isber S.; Tabbal, M. “One-dimensional coordination polymer [Co(H2O)4(pyz)](NO3)2·2H2O (pyz = pyrazine) with intra- and inter-chain H-bonds:  structure, electronic spectral studies and magnetic properties” Polyhedron 2005, 24, 221-228.  (full paper)
  • 33.  Mough, S. T.; Goeltz, J. C.(*); Holman, K. T. “Isolation and Structure of an ‘Imploded’ Cryptophane” Angew. Chem. Int. Ed. 2004, 43, 5631-5635.  (communication) http://onlinelibrary.wiley.com/doi/10.1002/anie.200460866/abstract
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  • 32.  Kandasamy, K.; Kumar, S.; Singh, H. B.; Butcher, R. J.; Holman, K. T.  "Synthesis, structural characterization and fluorescence properties of organoselenium compounds bearing a ligand containing both bulky and nonbonding groups - The first observation of both intramolecular Se···N and Se···O interactions in a diselenide structure" Eur. J. Inorg. Chem. 2004, 5, 1014-1023.  (full paper)
  • 31.  Holman, K. T. “Cryptophanes:  Molecular Containers” In Encyclopedia of Supramolecular Chemistry; J. A. Atwood, J. W. Steed, Eds., Marcel Dekker: New York, NY 2004; pp. 340-348. (short review)
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  • 30.  Gaunt, A. J.; May, I.; Copping, R.; Bhatt, A. I.; Collison, D.; Fox, O. D.; Holman, K. T.; Pope, M. T. “A new structural family of heteropolytungstate lacunary complexes with the uranyl, UO22+, cation,” Dalton Trans. 2003, 3009-3014.  (full paper)
  • 29.  Gaunt, A. J.; May, I.; Collison, D.; Holman, K. T.; Pope, M. T. “Polyoxometal cations within polyoxometalate anions.  Seven-coordinate uranium and zirconium heteroatom groups in [(UO2)12(m3-O)4(m2-H2O)12(P2W15O56)4]32- and [Zr4(m3-O)2(m2-OH)2(H2O)4(P2W16O59)2]14-,” J. Mol. Struct. 2003, 656, 101-106.  (full paper)
University of Minnesota (postdoctoral work)…
  • 28.  Horner, M. J.; Grabowski, S.; Sandstrom, K.; Holman, K. T.; Bader, M.; Ward, M. D.; Kim, W.-S. “Hydrogen-bonded host frameworks with tunable cavities:  Structural characterization and inclusion-based separations of molecular isomers” ACA Transactions 2004, 39(15), 1-10.  (full paper)
  • 27.  Holman, K. T.; Pivovar, A. M.; Ward, M. D. “Engineering crystal symmetry and polar order in molecular host frameworks,” Science 2001, 294, 1907-1911. (full paper) http://www.sciencemag.org/cgi/content/abstract/294/5548/1907
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  • 26.  Horner, M. J.; Holman, K. T.; Ward, M. D. “Lamellae-nanotube isomerism in hydrogen-bonded host frameworks,” Angew. Chem. Int. Ed. 2001, 40, 4045-4048. (communication) http://onlinelibrary.wiley.com/doi/10.1002/1521-3773(20011105)40:21%3C4045::AID-ANIE4045%3E3.0.CO;2-J/full
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  • 25.  Pivovar, A. M.; Holman, K. T.; Ward, M. D. “Shape selective separation of molecular isomers with adjustable hydrogen-bonded host frameworks,” Chem. Mater. 2001, 13, 3018-3031. (full paper) http://pubs.acs.org/doi/abs/10.1021/cm0104452
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  • 24.  Holman, K. T.; Martin, S. S.; Parker, P. P.; Ward, M. D. “The generality of architectural isomerism in designer inclusion frameworks,” J. Am. Chem. Soc. 2001, 123, 4421-4431. (full paper) http://pubs.acs.org/doi/abs/10.1021/ja0030257
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  • 23.  Holman, K. T.; Swift, J. A.; Pivovar, A. M.; Ward, M. D. “Metric engineering of soft molecular host frameworks” Acc. Chem. Res. 2001, 34, 107-118. (short review)  http://pubs.acs.org/doi/abs/10.1021/ar970272f
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  • 22.  Holman, K. T.; Ward, M. D. “Crystal engineering with soft and topologically adaptable molecular host frameworks” In Stimulating Concepts in Chemistry; Stoddart, J. F.; Vögtle, F. Shibasaki, M. (Eds.); Wiley-VCH: Weinheim, 2000; pp. 221-236. (short review) 
  • 21.  Plaut, D. J.; Holman, K. T.; Pivovar, A. M.; Ward, M. D. “Building molecular frameworks with tailored pore structures” J. Phys. Org. Chem. 2000, 13, 858-869. (short review)  doi.org/10.1002/1099-1395(200012)13:12%3C858::AID-POC318%3E3.0.CO;2-S
  • 20.  Holman, K. T.; Ward, M. D. “Metric engineering of crystalline inclusion compounds by structural mimicry” Angew. Chem. Int. Ed. 2000, 39, 1653-1656. (communication) http://onlinelibrary.wiley.com/doi/10.1002/%28SICI%291521-3773%2820000502%2939:9%3C1653::AID-ANIE1653%3E3.0.CO;2-7/abstract
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University of Missouri-Columbia (graduate work)…
  • 19.  Hogarth, G.; Holman, K. T.; Pateman, A.; Sella, A.; Seed, J. W.; Richards, I. “Multiple nitrene insertions into metal-sulfur bonds of dithiocarbamate complexes: synthesis of sulfido-amido and zwitterionic tetraamido complexes” Dalton Trans. 2005, 2688-2695.  (full paper)
  • 18.  K. Travis Holman and Jerry L. Atwood “Metallated calixarenes and cyclotriveratrylenes as anion hosts” In Fundamentals and Applications of Anions Separations; Moyer, B. A.; Singh, R. P., Eds.; American Chemical Society Meeting (2001, Chicago, Il.); Klewer Academic/Plenum Publishers: New York, 2004; pp 87-106.
  • 17.  Gawenis, J. A.; Holman, K. T.; Atwood, J. L.; Jurisson, S. S. “Extraction of pertechnetate and perrhenate from water with deep-cavity [CpFe(arene)]+-derivatized cyclotriveratrylenes” Inorg. Chem. 2002, 41, 6028-6031.  (full paper)
  • 16.  MacGillivray, L. R.; Holman, K. T.; Atwood, J. L.  “Hydrogen bonds assist the organization of up to 11 guests within self-assembling cavities of nanometer dimensions” J. Supramol. Chem. 2001, 1, 125-130. (full paper)
  • 15.  Elisabeth, E.; Barbour, L. J.; Orr, G. W.; Holman, K. T.; Atwood, J. L. “Synthesis and structure of a one-dimensional coordination polymer based upon a tetracyanocalix[4]arene in the cone conformation” Supramol. Chem. 2000, 12, 317-320.  (communication)
  • 14.  Holman, K. T.; Robinson, S. D.; Sahajpal, A.; Steed, J. W. “N,N',N''-Triphenylguanidinate complexes of ruthenium and palladium: synthesis and crystal structures” J. Chem. Soc., Dalton Trans. 1999, 15-18.  (full paper)
  • 13.  MacGillivray, L. R.; Holman, K. T.; Atwood, J. L. “Multi-guest inclusion within one-dimensional hydrogen bonded polymers based on C-methylcalix[4]resorcinarene” Trans. Am. Crystallogr. Assoc. 1999, 33, 129-133. (full paper)
  • 12.  Atwood, J. L.; MacGillivray, L. R.; Rose, K. N.; Barbour, L. J.; Holman, K. T.; Orr, G. W. “Large molecular assemblies held together by non-covalent bonds” NATO Sci. Ser., Ser. C 1999, 519, 7-16. (review)
  • 11.  Holman, K. T.; Orr, G. W.; Steed, J. W.; Atwood, J. L. “Deep cavity [CpFe(arene)]+ derivatized cyclotriveratrylenes as anion hosts” Chem. Commun. 1998, 2109-2110.  (communication)
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  • 10.  Staffilani, M.; Bonvicini, G.; Steed, J. W.; Holman, K. T.; Atwood, J. L.; Elsegood, M. R. J. “Bowl vs. saddle conformations in cyclononatriene-based anion binding hosts” Organometallics 1998, 17, 1732-1740. (full paper)
  • 9.   MacGillivray, L. R.; Holman, K.T.; Atwood, J.L. “One-dimensional hydrogen bonded polymers based on C-methyl-calix[4]resorcinarene and a crystal engineering design strategy” Crystal Engineering 1998, 1(1), 87-96. (full paper) 
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  • 8.   Holman, K. T.; Atwood, J. L.; Steed, J. W. “Supramolecular anion receptors” In Advances in Supramolecular Chemistry; G. W. Gokel, Ed.; JAI Press: Greenwich, CT, 1997; vol. 4, pp 287-330. (review)
  • 7.   Holman, K. T.; Steed, J. W.; Atwood, J. L. “Intra-cavity inclusion of [CpFeII(arene)]+ guests by cyclotriveratrylene.” Angew. Chem., Int. Ed. Engl. 1997, 36, 1736-1738; ¾ Angew. Chem. 1997, 109, 1840-1842.  (communication)
  • 6.   Staffilani, M.; Hancock, K. S. B.; Steed, J. W.; Holman, K. T.; Atwood, J. L.; Juneja, R. K.; Burkhalter, R. S. “Anion binding within the cavity of p-metalated calixarenes” J. Am. Chem. Soc. 1997, 119, 6324-6335. (full paper)        
  • 5.   Holman, K. T.; Halihan, M. M.; Mitchell, A. R.; Burkhalter, R. S.; Steed, J. W; Jurisson, S. S.; Atwood, J. L. “Inclusion of neutral and anionic guests within the cavity of p-metalated cyclotriveratrylenes” J. Am. Chem. Soc. 1996, 118, 9567-9576. (full paper) 
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  • 4.   Steed, J. W.; Holman, K. T.; Atwood, J. L. “Laying traps for elusive prey: Recent advances in the non-covalent binding of anions” Chem. Commun. 1996, 1401-1407. (review)
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  • 3.   Holman, K. T.; Halihan, M. M.; Steed, J. W.; Jurisson, S. S.; Atwood, J. L. “Hosting a radioactive guest: binding of 99TcO4- by a metalated cyclotriveratrylene” J. Am. Chem. Soc. 1995, 117, 7848-7849. (communication)
Saint Mary’s University (undergraduate work)…
  • 2.   Copp, S. B.; Holman, K. T.; Sangster, J. O. S.; Subramanian, S.; Zaworotko, M. J. “Supramolecular chemistry of [M(CO)3(m3-OH)]4 (M = Mn or Re): A modular approach to crystal engineering of superdiamondoid networks.” J. Chem. Soc., Dalton Trans. 1995, 2233-2243. (full paper) DOI: 10.1039/DT9950002233; http://pubs.rsc.org/en/content/articlepdf/1995/dt/dt9950002233
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  • 1.  Holman, K. T.; Zaworotko, M. J. “Crystal and molecular structure of [Mn(CO)3(m3-OH)]4” J. Chem. Cryst. 1995, 25, 93-95. (communication)
Editorials:
  • 1.   Holman, K. T. Supramolecular Chemistry 2014, 26, 139-140.  Editorial for Special Issue commemorating the 8th International Symposium on Macrocyclic and Supramolecular Chemistry. DOI: 10.1080/10610278.2014.893075
Book Reviews:
  • 1.   Holman, K.T. “Review: Making Crystals by Design:  Methods, Techniques and Applications” J. Am Chem. Soc. 2008, 130, 2878-2878.  (book review) http://pubs.acs.org/doi/abs/10.1021/ja0769090  

Patents and Patent Applications
  • Holman, K. T., “Cryptophane derivatives and methods of use thereof,” Assignee: Georgetown University, USA; Patent No. WO 2012/051323 A2, Apr 19, 2012; Application No. WO 2011-US55993, Oct 12, 2011; Priority Application US 2010-392226P.  The present invention relates to the cryptophane derivatives capable of encapsulating small molecules such as noble gases for biological and environmental use.  In particular, the invention relates to cryptophane derivatives with high affinity for xenon, which can be used as biosensors in clinical imaging and biosensing. 
  • New Provisional Patent Application, Serial No. 61/614,967, Holman, K. T.; Kane, C. M. “Cavitand Compositions and Methods of Use Thereof”, filing date:  March 23, 2012. The present invention relates to crystalline forms of cavitand derivatives and their use in the separation, by selective inclusion, and/or storing of small molecule gases. 

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